I'm not that into the show the 100, and I've heard it ends terribly, so I probably won't be watching it anytime soon, but I am into TW and I thought pairing Octavia and Derek would be really interesting. Sorry for making Bellamy the bad guy for a little while here, but the idea was that werewolves survived the radiation and their packs are the Grounders still left on Earth. Some werewolves attack Octavia and Derek protects her, but the 100 are afraid of werewolves and they take him prisoner. Octavia ends up setting him free and they fall in love.

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